Accurate and Sensitive Determination Method for Procymidone and Chlorflurenol in Municipal Wastewater, Medical Wastewater and Irrigation Canal Water by GC–MS After Vortex Assisted Switchable Solvent Liquid Phase Microextraction

Kapukıran F., Fırat M., Chormey D. S., BAKIRDERE S., Özdoğan N.

Bulletin of Environmental Contamination and Toxicology, cilt.102, sa.6, ss.848-853, 2019 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 102 Sayı: 6
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1007/s00128-019-02618-w
  • Dergi Adı: Bulletin of Environmental Contamination and Toxicology
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.848-853
  • Anahtar Kelimeler: Chlorflurenol, GC–MS, Pesticide, Procymidone, Switchable solvent
  • İstanbul Gelişim Üniversitesi Adresli: Hayır

Özet

In this study, the detection power of a gas chromatography mass spectrometer (GC–MS) for procymidone and chlorflurenol was significantly enhanced using switchable solvent liquid phase microextraction (SS-LPME) as a preconcentration tool. This was achieved by a comprehensive optimization of significant parameters to the SS-LPME method such as switchable solvent amount, concentration and amount of sodium hydroxide, pH effect and mixing effect. The optimum experimental conditions obtained were used to determine analytical figures of merit for the analytes. The limits of detection obtained were 0.44 and 2.9 ng/mL for procymidone and chlorflurenol, respectively. The optimum method was applied to water sampled from an irrigation canal and two wastewater samples. The samples were spiked at two concentrations and the percent recovery results obtained ranged between 86 and 115% for both analytes. The recovery results together with the low standard deviations recorded validated the method as accurate and precise.