Decalin-assisted light emitting porous Si formation and its optical, surface and morphological properties


Karatutlu A., Istengir S., Cosgun S., Seker I., Unal B.

Applied Surface Science, vol.422, pp.498-503, 2017 (SCI-Expanded, Scopus) identifier

  • Publication Type: Article / Article
  • Volume: 422
  • Publication Date: 2017
  • Doi Number: 10.1016/j.apsusc.2017.06.057
  • Journal Name: Applied Surface Science
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.498-503
  • Keywords: Chemical etching, Confocal microscopy, Lep-Si, Photoluminescence, Surfactant
  • Istanbul Gelisim University Affiliated: No

Abstract

In this research paper, light emitting porous silicon (Lep-Si) samples were fabricated by a surfactant-mediated chemical stain etching solution in order to form homogenous luminescent nanostructures at room temperature. As an industrially important solvent, decalin (decahydronaphtalene) was used as a surfactant in the HF/HNO 3 solutions in order to control the etching process. Morphological, surface and optical properties of the Lep-Si samples were examined using atomic force microscopy, X-ray photoelectron spectroscopy, photoluminescence (PL) spectroscopy, and laser scanning confocal microscopy (LSCM) techniques. These characterization techniques were correlated with the various etching times including depth dependent luminescence profiles for the first time. We report the optimum conditions for production of the most efficient Lep-Si using decalin (decahydronaphtalene) and possible structural origins of light emission using the depth dependent luminescence measurements.