Template synthesis and spectral characterization of new Lead(II)-Schiff base macrocyclic complexes incorporating phenanthroline and/or bipyridine units

Beynek N., Tan N., Beynek H.

Asian Journal of Chemistry, vol.27, no.11, pp.4141-4144, 2015 (Scopus) identifier

  • Publication Type: Article / Article
  • Volume: 27 Issue: 11
  • Publication Date: 2015
  • Doi Number: 10.14233/ajchem.2015.19135
  • Journal Name: Asian Journal of Chemistry
  • Journal Indexes: Scopus
  • Page Numbers: pp.4141-4144
  • Keywords: Bipyridine, Lead(II), Macrocyclic complex, Phenanthroline, Schiff base, Template reactions
  • Istanbul Gelisim University Affiliated: Yes

Abstract

Lead(II) complexes of Schiff-bases containing phenanthroline and/or bipyridine units were synthesized by the template reaction between new diamine compound, 6,6'-bis(2-aminophenoxymethyl)-2,2'-bipyridine and 2,2-bipyridine-6,6-dicarboxaldehyde or 1,10-phenanthroline- 2,9-dicarboxaldehyde in the presence of metal ions. These complexes, [PbL1]( ClO4)2and [PbL2](NO3)2, were characterized and investigated by using; MALDI-TOF and Q-TOF-MS spectroscopy, FTIR, UV/Visible spectroscopy, 1H NMR, Elemental analyses (CHN), magnetic susceptibility and molar conductivity measurements.