Thermal properties of cellulose nanofibrils and nickel-titanium alloy-reinforced sustainable smart composites


Yildirim M., Mutlu İ., Candan Z.

Wood Material Science and Engineering, cilt.19, sa.3, ss.557-563, 2024 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 19 Sayı: 3
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1080/17480272.2023.2267513
  • Dergi Adı: Wood Material Science and Engineering
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aerospace Database, Agricultural & Environmental Science Database, Applied Science & Technology Source, CAB Abstracts, Communication Abstracts, Compendex, INSPEC, Metadex, Veterinary Science Database, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.557-563
  • Anahtar Kelimeler: Alloy, lignocellulosic bionanomaterials, smart composites, thermal properties
  • İstanbul Gelişim Üniversitesi Adresli: Evet

Özet

The study focused on the synergistic effect of cellulose nanofibrils (CNFs) as a lignocellulosic bionanomaterial and nickel-titanium (NiTi) alloy as a shape memory smart metallic material reinforcer on the thermal properties of sustainable smart composites. The casting process was used to produce composites with CNF loadings of 1%, 3%, and 5% and NiTi loadings of 3% into epoxy resin. Thermal properties were evaluated using thermogravimetric (TGA), derivative thermogravimetric (DTG), differential scanning calorimetry (DSC), and dynamic mechanical thermal (DMTA) analysis. The TGA results revealed that the CNF/NiTi-reinforced groups have considerable higher degradation temperatures and thermal stability than the control group. Also, at 800°C, CNF/NiTi-reinforced groups had a higher residual content than the control group. DTG results showed that the addition of CNFs decreased the degradation speed. Although the NiTi loading was constant, it was determined that the addition of CNFs increases the storage modulus (E′), loss modulus (E″), tan delta (Tan δ), and glass transition temperature (Tg). Overall, it can be concluded that CNF/NiTi-reinforced composites indicated significantly improved thermal stability, decomposition temperature, residual content, elastic, and viscous properties. These smart composites can be used for advanced material applications requiring thermal stability.