Journal of Vacuum Science and Technology B: Nanotechnology and Microelectronics, vol.34, no.6, 2016 (SCI-Expanded)
Dry etching of silicon has been extensively studied, mostly with a goal of obtaining perfectly vertical sidewalls with high aspect ratio. Yet, sloped sidewall with a negative taper angle (i.e., diameter/width decreases linearly with depth) may find various applications. However, the systematic study on the etching process development to obtain such a profile is rather scarce. In this work, the authors present a controlled and reproducible fabrication process to achieve silicon nanostructures with negatively tapered sidewall profile using inductively coupled plasma-reactive ion etching with C4F8 and SF6 gas. The plasma etching parameters have been thoroughly optimized in order to avoid the undercut or curved reentrant profile due to isotropic etching, so as to achieve a negatively tapered profile. The influence of the plasma etching parameters, especially the radio freguency power and C4F8/SF6 gas flow ratio, on the etching rate and the sidewall taper angle has been analyzed. With an optimal etching recipe, the silicon nanostructures with an unprecedented large 10° negative taper angle were achieved. These results were demonstrated on different structure sizes of 500 nm, 700 nm, and 1.2 μm diameters.